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郭放
2017-03-05 21:23  

 

IMG_0335

郭放,英国卡迪夫大学博士、博士后。辽宁大学研究员,博士生导师。辽宁省百千万人才工程百人层次、辽宁大学辽河学者,第二梯队学术带头人,辽宁省高等学校优秀青年学者。

    研究方向为固态超分子化学及其晶体工程,主要包括超分子及其药物分子的晶体生长、同质多晶、结构与性能关系研究;二次球配位超分子化学;超分子化学的固态合成;有机化合物的粉末衍射结构测定。

近年来先后承担国家自然科学基金3项(2项面上,1项青年),辽宁省优秀人才青年学者资助计划、教育部回国留学人员基金等项目的研究工作。J. Am. Chem. Soc.Chem. Commun.Cryst. Growth & Des.J. Phys. Chem. CDolton. Trans.Inorg. Chem.CrystEngComm等国际期刊发表SCI论文60余篇,其中影响因子大于4.0的国际化学权威期刊20余篇。国内授权发明专利2项。曾荣获辽宁大学振兴奖,辽宁省自然科学学术成果奖多项。

主要论著(第一作者或者通讯作者)

1.        Exploiting polymorphism in second sphere coordination: thermal transformation, NLO properties and  selective mechanochemical synthesis, CrystEngComm, 2016, 18, 2408–2412.

2.        Crystal engineering of a hybrid metal–organic host framework and its single-crystal-to-single-crystal guest exchange using second sphere coordination, CrystEngComm, 2016, 18, 2284–2288.

3.        High-Efficiency Deep-Red Quantum-Dot Light-Emitting Diodes with Type-II CdSe/CdTe Core/Shell Quantum Dots as Emissive Layers, J. Mater. Chem. C, 2016, 4, 7223-7229.

4.        Second Sphere Coordination of Hybrid Metal-Organic Materials: Solid State Reactivity, Dalton Trans., 2016, 45, 13648-13662. (Perspective)

5.        Insights into the formation of chiral second sphere coordination complexes with aromatic tris amines: combined single    crystal X-ray crystallography and molecular modeling analyses, Dalton Trans., 2015, 44, 15960–15965.

6.        Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands, Cryst. Growth Des., 2015, 15, 2842-2852.

7.        Cadmium-free quantum dots based violet light-emitting diodes: High-efficiency and brightness via optimization of organic hole transport layers, Org. Electronics, 2015, 25: 178-183.

8.  Cyclic Interconversion among Molecular Salts via Neat Grinding and Related Photoluminescence Properties, Cryst. Growth Des., 2014, 14, 65286536.

9.  A second sphere coordination adduct containing one-dimensional water/methanol channels: X-ray structures, thermal stability and single crystal impedance spectroscopy analysis, CrystEngComm, 2014, 16, 10888–10892.

10.  Synthesis of Chelating Complexes through Solid-State Dehydrochlorination Reactions via Second-Sphere-Coordination Interaction with Metal Chlorides: A Combined ExperimentalMolecular Modeling Study, Inorg. Chem. , 2014, 53, 74387445.

11.  Mechanochemical dehydrochlorination and chelation reaction in the solid state: from a molecular salt to a coordination complex, CrystEngComm, 2014, 16, 969-973.

12.  Solid state transformations in stoichiometric hydrogen bonded molecular salts: ionic interconversion and dehydration processes, CrystEngComm, 2013, 15, 6237-6243.

13.  Polymorphism and photoluminescence in a naphthalene-based ligand, and its supramolecular structures through second-sphere coordination with the [CoCl4]2- anion, RSC Adv., 2013, 3, 11594.

14.  Co-crystal of [CuCl4]2- and L1 and its inclusion compounds with three different guests (L1 = N, N, N′, N′ - tetra-p-methoxybenzyl – ethylenediamine), CrystEngComm, 2011, 13,6753-6758.

15.  Supramolecular inclusion of a pillared double-layered host by anion-directed second-sphere coordination, Supramol. Chem., 2010, 22, 9, 548-553.

16.  Direct structural understanding of a topochemical solid state photopolymerization reaction, J. Phys. Chem. C, 2008, 112, 19793-11796.

17.  On the spontaneous induction of chirality in the preparation of Werner’s complex cis-[CoBr(NH3) (en)2]Br2,  Chem. Commun., 2006, 1854-1856.

18.  Abundant polymorphism in a system with multiple hydrogen-Bonding opportunities: oxalyl Dihydrazide, J. Am. Chem. Soc., 2006, 128, 8441-8452.

19.  Contrasting solid-State structures of trithiocyanuric acid and cyanuric acid, Cryst. Growth & Des., 2006, 6, 846-848.

20.  Structural understanding of a molecular material that is accessed only by a solid-State desolvation process: The Scope of Modern Powder X-ray Diffraction Techniques, J. Am. Chem. Soc., 2005, 127, 7314-7315.

专利

1.一种采用超分子二次球形配位识别分离富集钯的方法, ZL 2009 1 0010882.9,

2.包结结晶法提取蛇床子中甲氧基欧芹素和欧前胡素的方法,ZL 2011 1 0329004.0

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